Thermodynamics and statistical mechanics scott shell pdf
CHE 210A: Thermodynamics and statistical mechanics
The patterning of interfaces, both chemical and structural, directs an enormous range of thermodynamic and dynamic properties of the fluids that meet them. Here, we present two examples where molecular simulations allow systematic charting of the effects of different interfacial configurations, which in turn offers design principles for engineering desired structures and behaviors. In the first, we examine a route to chiral surfaces through the selfassembly of achiral, quasi 2D colloidal particles of tunable shapes. We show that a surprisingly simple mechanism, based only on excluded volume interactions, can drive achiral particles into chiral materials. The mechanism quantitatively explains recent experimental results, predicts new chiralprone shapes, and suggests a way that chiral structures might emerge in nature. We develop a novel genetic optimization algorithm, coupled to iterative molecular dynamic simulations, that designs the arrangement of surface groups so as to minimize or maximize the diffusion nearby water.
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Statistical Thermodynamics l Mechanics - Asst. Prof. Aditi Joshi
He earned his PhD in Chemical Engineering from Princeton in and is well known for his ability to communicate complex ideas and teach in an engaging manner. Scott Shell. Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics.